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Re: CopperPosted by mark on May 3, 2001 at 17:15:14: In reply to: Re: Copper posted by Catherine Cartwright Jones on May 3, 2001 at 16:45:59: : Copper oxides are used in some khidab and some harquuses ....but.... : the toxicity bothers me. Copper is a tad poisonous. I tried mixing : henna with copper oxide ... no dif that I could see. I tried throwing : pennies into a batch. No real dif that I could see. : : Anyway .. it makes the henna go drabber, if anything, (and I've not : seen much evidence of that) not redder. : : It doesn't make it last longer. : : Most of the metal oxides do not penetrate the skin at all : (fortunate!). : Once I added black iron oxide to the mix, and for a brief moment, I : thought the henna was MUCH darker ...BUT ... I rinsed my hands and : away went the black! It was just sitting there. Never penetrated at : all. : : I think it is possible that perspiration interacts with metal and : creates a condition that favors much darker henna ...but that's : chemically a bit beyond my ken. Some of the metal mixing bowls from : India are silver-colored but have a high copper content. I don't : think copper is actually getting into the henna, but the acidity of : the paste is reacting with the copper to change something. Copper is : very reactive with oxygen, and that might be changing that loose H, or : the double bound O on the hennotannic acid molecule. Henna paste : appears blacker when it touches copper, but I haven't seen it stain : blacker. Many natural dyes change color dramatically when you simmer : the acidic dyebath in copper vs enamel pots. The copper oxide does : seem to percipitate some vegetal acidic dyes into another : color,(usually drab and dark) but beyond telling you that, I can't : help. Oak gall dyes (gallotannins, related to hennotannins) will : stain darker if a handful of copper salts are thrown into the dye ... : but its a poisonous thing to do. : : Many of the pre-made pastes have some heavy metal oxides, that seem to : be be behaving similarly to what I just described. They make henna : darker.... maybe... but the color is that drabbish color, not the : vibrant natural henna color. And ... : : Do you really want to put something into henna that is an : environmental yucko? Copper oxides can be nasty when not in their : proper place. It was a debate at the studio yesterday .....why i was asking. I would personally not like to add it to henna ......the debate was why use silver or copper bowls for mixing!
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